I don't think that can happen. Though shown to be capable of learning, Xenomorphs seem to act much more on animal instinct. Also, while it may not pertain to 5YL, Derrick Wyatt confirmed they wouldn't be accepted into the Omnitrix. They could go in the Nemetrix though.
They are pretty smart in Alien: Isolation, because they do get over their fear of fire and learn about your hiding spots, plus they got that scorpion tail and acid blood, but other than that, pretty cute compared to the rest of the predators (Maybe better than the Panuncian since all It does is multiply...)